Cheaper, longer lasting dye-sensitized solar cells

Dye-sensitized solar cells have long held the promise of cheap, easy to make solar cells, but it’s been difficult for the companies involved to actually make and sell them.   But last week there was an announcement out of Northwestern University that could change that.   The Northwestern University research team came up with a more efficient dye-sensitized cell that eliminates one of its biggest drawbacks – the prone to leak corrosive liquid electrolyte.

Dye-sensitized solar cells work by using the incoming light to excite a layer of titanium dioxide (also known as titania) coated with the dye.   This causes positive and negative charges to be generated – the negative electrons flow out of the cell – the positive charges flow into the liquid electrolyte.   But up to now, these cells were prone to leaking, especially when things got hot – the liquid electrolyte expanded and sometimes ruptured the seals.    To make matters worse, the corrosive electrolyte also had a tendency to eat through aluminum and stainless steel.

The team, which consisted of chemist Mercouri Kanatzidis, materials scientist Robert Chang, and two graduate students, developed a solid iodine-based semiconductor to replace the corrosive liquid electrolyte.   Previous designs using solid electrolyte designs have suffered from low efficiency, but the new design has proven to actually boost performance, since their new electrolyte also absorbs light.   Kanatzidis says that the electrolyte “actually absorbs more light than the dye itself.”

They’ve developed solar cells that convert 10.2 percent of light to electricity – up to now solid-state dye sensitized cells have only hit about 7 percent. While still lower than silicon based solar cells and even thin-film solar cells, the cost of manufacturing these new dye-sensitized cells should be even lower.

The colored windows are Dyesol dye-sensitized solar cells used in a window
Dyesol dye-sensitized solar cell
But not all dye-sensitized solar cell companies are convinced that the solid state cells are better.   Dyesol, an Australian company, has been working on its liquid electrolyte cells and have produced cells that have shown, in accelerated testing, longevity equal to a 25 year lifespan.  They’re working on integrating their cells into building materials like glass panels and steel roofing sheets.

 

via: MIT Technology Review

 

 

5 thoughts on “Cheaper, longer lasting dye-sensitized solar cells

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  5. On August 2006, to prove the chemical and thermal robustness of the 1-ethyl-3 methylimidazolium tetracyanoborate solar cell, the researchers subjected the devices to heating at 80 °C in the dark for 1000 hours, followed by light soaking at 60 °C for 1000 hours. After dark heating and light soaking, 90% of the initial photovoltaic efficiency was maintained – the first time such excellent thermal stability has been observed for a liquid electrolyte that exhibits such a high conversion efficiency. Contrary to silicon solar cells , whose performance declines with increasing temperature, the dye-sensitized solar-cell devices were only negligibly influenced when increasing the operating temperature from ambient to 60 °C.

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